A Charge-Transfer Salt Based on Ferrocene/Ferrocenium Pairs and Keggin-Type Polyoxometalates.

ABSTRACT: A new hybrid inorganic-organometallic salt has been obtained from the reaction of the Keggin-type silicotungstate anion with ferrocene in a water/methanol mixture as a result of the partial oxidation of ferrocene molecules to ferrocenium cations. Single-crystal X-ray diffraction analysis reveals the presence of four ferrocenium (Fe^III) cations and one ferrocene (Fe^II) molecule per plenary Keggin anion in the crystal structure of [Fe^III (Cp)₂]₄[SiW₁₂O₄₀]·[Fe^II(Cp)₂]·2CH₃OH (1). Compound 1 thus constitutes the first example in the literature in which ferrocenium and ferrocene species coexist in the structure of a polyoxometalate-based salt. The two crystallographically independent ferrocenium species in the asymm

SUBMITTER: Artetxe B 

PROVIDER: S-EPMC6321299 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature