Time-Resolved Spectroscopic Study of N,N-Di(4-bromo)nitrenium Ions in Selected Solutions.

ABSTRACT: Nitrenium ions are important reactive intermediates in chemistry and biology. In this work, femtosecond and nanosecond transient absorption (fs-TA and ns-TA) along with nanosecond time-resolved resonance Raman (ns-TR³) experiments were employed to examine the photochemical pathways of N-(4,4'-dibromodiphenylamino)-2,4,6-trimethylpyridinium BF₄- (salt (DN) from just absorption of a photon of light to the production of the important N,N-di(4-bromophenyl)nitrenium ion 2. In acetonitrile (MeCN), the formation of halogenated diarylnitrenium ion 2 was observed within 4 ps, showing the vibrational spectra with strong intensity. The nucleophilic adduct reaction of ion 2 with H₂O was also examined in aqueous solutions. The direct detection of the unique ortho adduct intermediate 3 shows that there

SUBMITTER: Du L 

PROVIDER: S-EPMC6321521 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature