Cationic Hofmeister Series of Wettability Alteration in Mica-Water-Alkane Systems.

ABSTRACT: The specific interaction of ions with macromolecules and solid-liquid interfaces is of crucial importance to many processes in biochemistry, colloid science, and engineering, as first pointed out by Hofmeister in the context of (de)stabilization of protein solutions. Here, we use contact angle goniometry to demonstrate that the macroscopic contact angle of aqueous chloride salt solutions on mica immersed in ambient alkane increases from near-zero to values exceeding 10°, depending on the type and concentration of cations and pH. Our observations result in a series of increasing ability of cations to induce partial wetting in the order Na⁺, K⁺ < Li⁺ < Rb⁺ < Cs⁺ < Ca²⁺ < Mg²⁺ < Ba²⁺. Complementary atomic

SUBMITTER: Bera B 

PROVIDER: S-EPMC6328296 | biostudies-literature | 2018 Nov

REPOSITORIES: biostudies-literature