Reducing aggregation caused quenching effect through co-assembly of PAH chromophores and molecular barriers.

ABSTRACT: The features of well-conjugated and planar aromatic structures make π-conjugated luminescent materials suffer from aggregation caused quenching (ACQ) effect when used in solid or aggregated states, which greatly impedes their applications in optoelectronic devices and biological applications. Herein, we reduce the ACQ effect by demonstrating a facile and low cost method to co-assemble polycyclic aromatic hydrocarbon (PAH) chromophores and octafluoronaphthalene together. Significantly, the solid photoluminescence quantum yield (PLQYs) for the as-resulted four micro/nanococrystals are enhanced by 254%, 235%, 474 and 582%, respectively. Protection from hydrophilic polymer chains (P123 (PEO₂₀-PPO₇₀-PEO₂₀)) endows the cocrystals with superb dispersibility in wat

SUBMITTER: Huang Y 

PROVIDER: S-EPMC6329816 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature