A bismuth oxide/graphene oxide nanocomposite membrane showing super proton conductivity and low methanol permeability.

ABSTRACT: Proton exchange membrane fuel cells are still limited as state-of-art proton exchange membranes perform poorly at high and low temperature and are easily damaged by harsh electrochemical conditions such as reactive peroxide species. One effective solution to this issue is to develop new types of proton conductive materials that are capable of working in a broad temperature range. A simple vacuum-assisted filtration method is employed to obtain a well-ordered new proton-conducting membrane by immobilizing nanosized bismuth oxide clusters [H6Bi12O16] (NO3)10·6(H2O) {H6Bi12O16} onto graphene oxide (GO) supports (named as {H6Bi12O16}/GO). {H6Bi12O16}/GO is stable in acidic media and has high proton conductivity over the temperature range from -40 to 80 °C. The proton conductivity of the {H6Bi1

SUBMITTER: Liu B 

PROVIDER: S-EPMC6334630 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature