Phthalimide-Based High Mobility Polymer Semiconductors for Efficient Nonfullerene Solar Cells with Power Conversion Efficiencies over 13.

ABSTRACT: Highly efficient nonfullerene polymer solar cells (PSCs) are developed based on two new phthalimide-based polymers phthalimide-difluorobenzothiadiazole (PhI-ffBT) and fluorinated phthalimide-ffBT (ffPhI-ffBT). Compared to all high-performance polymers reported, which are exclusively based on benzo[1,2-b:4,5-b']dithiophene (BDT), both PhI-ffBT and ffPhI-ffBT are BDT-free and feature a D-A₁-D-A₂ type backbone. Incorporating a second acceptor unit difluorobenzothiadiazole leads to polymers with low-lying highest occupied molecular orbital levels (≈-5.6 eV) and a complementary absorption with the narrow bandgap nonfullerene acceptor IT-4F. Moreover, these BDT-free polymers show substantially higher hole mobilities than BDT-based polymers, which are beneficia

SUBMITTER: Yu J 

PROVIDER: S-EPMC6343056 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature