Self-Assembly of Supramolecular Fractals from Generation 1 to 5.

ABSTRACT: In the seeking of molecular expression of fractal geometry, chemists have endeavored in the construction of molecules and supramolecules during the past few years, while only a few examples were reported, especially for the discrete architectures. We herein designed and constructed five generations of supramolecular fractals (G1-G5) based on the coordination-driven self-assembly of terpyridine ligands. All the ligands were synthesized from triphenylamine motif, which played a central role in geometry control. Different approaches based on direct Sonogashira coupling and/or ⟨tpy-Ru(II)-tpy⟩ connectivity were employed to prepare complex Ru(II)-organic building blocks. Fractals G1-G5 were obtained in high yields by precise coordination of organic or Ru(II)-organic building blocks with Zn(II)

SUBMITTER: Wang L 

PROVIDER: S-EPMC6348470 | biostudies-literature | 2018 Oct

REPOSITORIES: biostudies-literature