Topology and porosity control of metal-organic frameworks through linker functionalization.

ABSTRACT: Tetratopic organic linkers have been extensively used in Zr-based metal-organic frameworks (MOFs) where diverse topologies have been observed. Achieving meticulous control over the topologies to tune the pore sizes and shapes of the resulting materials, however, remains a great challenge. Herein, by introducing substituents to the backbone of tetratopic linkers to affect the linker conformation, phase-pure Zr-MOFs with different topologies and porosity were successfully obtained under the same synthetic conditions. The conversion of CO₂ to valuable cyclic carbonates is a promising route for the mitigation of the greenhouse gas. Owing to the presence of substrate accessible Lewis acidic Zr(iv) sites in the 8-connected Zr₆ nodes, the Zr-MOFs in this study have been inve

SUBMITTER: Lyu J 

PROVIDER: S-EPMC6349059 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature