Organic core-shell-shaped micro/nanoparticles from twisted macrocycles in Schiff base reaction.

ABSTRACT: Functional self-assemblies derived from noncovalent interactions such as lipid vesicles and DNA chiral double helices are a typical feature of natural life activity. Because of this phenomenon, a self-assembly approach for various functional organic particles is a desirable objective in supramolecular chemistry. Here, we report the discovery of enantiomeric conformers from a twisted macrocyclic host (MH), which was obtained from an achiral precursor by Schiff base reaction. Further studies suggest that a series of unexpected and stable core-shell-based organic micro/nanospheres can be directly precipitated from a simple reaction solution with high yield. A single-crystal X-ray diffraction analysis of MH revealed that the unusual C-H···π interaction triggered self-assembly of

SUBMITTER: Chen H 

PROVIDER: S-EPMC6354836 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature