Nanocellulose-Block Copolymer Films for the Removal of Emerging Organic Contaminants from Aqueous Solutions.

ABSTRACT: The prevalence of emerging organic contaminants (EOCs) in ground and surface water has sparked the search for more effective methods to remove EOCs from the environment. In pursuit of a solution for this environmental concern, herein we present the development of reusable films based on cellulose nanofibers (CNFs) and the block copolymer, poly(4-vinylpyridine-b-ethylene oxide) (P4VP-PEO) to adsorb sulfamethoxazole (SMX) as an EOC model compound. We hypothesize that the adsorption of SMX was achieved mainly by π-π interactions between the pyridine functionalities of the block copolymer and the electron deficient phenyl group of the SMX. Preceding preparation of the films, CNFs were modified with the alkoxysilane trimethoxy(2-phenylethyl)silane (TMPES) to increase their stability in aqueous

SUBMITTER: Herrera-Morales J 

PROVIDER: S-EPMC6357086 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature