The existence and impact of persistent ferroelectric domains in MAPbI₃.

ABSTRACT: Methylammonium lead iodide (MAPbI₃) exhibits exceptional photovoltaic performance, but there remains substantial controversy over the existence and impact of ferroelectricity on the photovoltaic response. We confirm ferroelectricity in MAPbI₃ single crystals and demonstrate mediation of the electronic response by ferroelectric domain engineering. The ferroelectric response sharply declines above 57°C, consistent with the tetragonal-to-cubic phase transition. Concurrent band excitation piezoresponse force microscopy-contact Kelvin probe force microscopy shows that the measured response is not dominated by spurious electrostatic interactions. Large signal poling (>16 V/cm) orients the permanent polarization into large domains, which show stabilization over weeks. X-ray

SUBMITTER: Garten LM 

PROVIDER: S-EPMC6357725 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature