Construction of alkyl-substituted pentaphosphido ligands in the coordination sphere of cobalt.

ABSTRACT: Rare mono- and diorganopentaphosphido cobalt complexes are accessible by P-P condensation using the unprecedented, reactive cobalt-gallium tetraphosphido complex [K(dme)₂{(^MesBIAN)Co(μ-η⁴:η²-P₄)Ga(nacnac)}] (2). Compound 2 was prepared in good yield by reaction of [K(Et₂O){(^MesBIAN)Co(η⁴-1,5-cod)}] [1, BIAN = bis(mesitylimino)acenaphthene diimine, cod = 1,5-cyclooctadiene] with [Ga(nacnac)(η²-P₄)] (nacnac = CH[CMeN(2,6-iPr₂C₆H₃)]₂). Reactions with R₂PCl (R = iPr, tBu, and Cy) selectively afford [(^MesBIAN)Co(cyclo-P₅R₂)] (3a-c), which feature η⁴

SUBMITTER: Ziegler CGP 

PROVIDER: S-EPMC6357856 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature