Air-stable redox-active nanomagnets with lanthanide spins radical-bridged by a metal-metal bond.

ABSTRACT: Engineering intramolecular exchange interactions between magnetic metal atoms is a ubiquitous strategy for designing molecular magnets. For lanthanides, the localized nature of 4f electrons usually results in weak exchange coupling. Mediating magnetic interactions between lanthanide ions via radical bridges is a fruitful strategy towards stronger coupling. In this work we explore the limiting case when the role of a radical bridge is played by a single unpaired electron. We synthesize an array of air-stable Ln₂@C₈₀(CH₂Ph) dimetallofullerenes (Ln₂ = Y₂, Gd₂, Tb₂, Dy₂, Ho₂, Er₂, TbY, TbGd) featuring a covalent lanthanide-lanthanide bond. The lanthanide spins are glued together by ver

SUBMITTER: Liu F 

PROVIDER: S-EPMC6362165 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature