Crystal structure determination of two pyridine derivatives: 4-[(E)-2-(4-meth-oxy-phen-yl)ethen-yl]-1-methyl-pyridin-1-ium hexa-fluoro-λ⁶-phosphane and 4-{(E)-2-[4-(di-methyl-amino)-phen-yl]ethen-yl}-1-phenyl-1λ⁵-pyridin-1-ylium hexa-fluoro-λ⁶-phosphane.

ABSTRACT: The title mol-ecular salts, C₁₆H₁₆NO⁺·PF₆ ^-, (I), and C₂₁H₂₁N₂ ⁺·PF₆ ^-, (II), are pyridine derivatives. In compound (I), the cation comprises a methyl N-substituted pyridine ring and a meth-oxy-substituted benzene ring connected by a C=C double bond. The F atoms of the PF₆ ^- anion are disordered over two sets of sites with refined occupancy factors of 0.614 (7):0.386 (7). In compound (II), the cation comprises a pyridine ring attached to unsubstituted phenyl ring and a di-methyl-aniline ring, which are connected by a C=C double bond. The anion is PF₆ ^-. In both salts, the cation adopts an E configuration with respect to

SUBMITTER: Mani JAM 

PROVIDER: S-EPMC6362639 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature