Crystal structure of bis(4-benzoyl-pyridine-κN)bis(methanol-κO)bis(thio-cyanato-κN)nickel(II) methanol monosolvate.

ABSTRACT: The asymmetric unit of the title compound, [Ni(NCS)₂(C₁₂H₉NO)₂(CH₃OH)₂]·CH₃OH, comprises one Ni^II cation, two thio-cyanate anions, two 4-benzoyl-pyridine coligands, two coordinating, as well as one non-coordinating methanol mol-ecule. The Ni^II cation is coordinated by two terminally N-bonded thio-cyanate anions, the N atoms of two 4-benzoyl-pyridine coligands and the O atoms of two methanol ligands within a slightly distorted octa-hedron. Individual complexes are linked by inter-molecular O-H⋯S hydrogen bonding into chains parallel to [010] that are further connected into layers parallel to (10) by C-H⋯S hydrogen bonds. Additional C-H⋯O hydrogen-bonding inter-actions lead to the formation of

SUBMITTER: Wellm C 

PROVIDER: S-EPMC6362648 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature