An unsymmetrical dinuclear scandium complex comprising salophen ligands [H₂salophen = N,N'-bis-(salicyl-idene)-1,2-phenyl-enedi-amine].

ABSTRACT: Treatment of scandium nitrate tetra-hydrate with the tetra-dentate ligand H₂salophen [N,N'-bis-(salicyl-idene)-1,2-phenyl-enedi-amine] afforded the yellow dinuclear complex Sc(NO₃)₂(μ-salophen)Sc(salophen)(EtOH) or [Sc₂(C₂₀H₁₄N₂O₂)₂(NO₃)₂(C₂H₆O)] (systematic name: (ethanol-κO)bis-(nitrato-κ² O,O'){μ-2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idene)]diphenolato-κ⁴ N,N',O,O':κ² O,O'}{2,2'-[1,2-phenyl-enebis(nitrilo-methanylyl-idene)]diphenolato-κ⁴ O,N,N',O'}discandium). In this compound, one salophen liga

SUBMITTER: Lorenz V 

PROVIDER: S-EPMC6362673 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature