Permanent porous hydrogen-bonded frameworks with two types of Bronsted acid sites for heterogeneous asymmetric catalysis.

ABSTRACT: The search for porous materials with strong Brønsted acid sites for challenging reactions has long been of significant interest, but it remains a formidable synthetic challenge. Here we demonstrate a cage extension strategy to construct chiral permanent porous hydrogen-bonded frameworks with strong Brønsted acid groups for heterogeneous asymmetric catalysis. We report the synthesis of two octahedral coordination cages using enantiopure 4,4',6,6'-tetra(benzoate) ligand of 1,1'-spirobiindane-7,7'-phosphoric acid and Ni₄/Co₄-p-tert-butylsulfonylcalix[4]arene clusters. Intercage hydrogen-bonds and hydrophobic interactions between tert-butyl groups direct the hierarchical assembly of the cages into a permanent porous material. The chiral phosphoric acid-containing framewor

SUBMITTER: Gong W 

PROVIDER: S-EPMC6363736 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature