ZnO Synthesized Using Bipolar Electrochemistry: Structure and Activity.

ABSTRACT: The photoactive materials broadly applied in catalysis and energy conversion are generally composed of metal oxides. Among these oxides, ZnO showed a promising photocatalytic activity; however, traditional synthetic routes generated by-products and large amounts of secondary waste. Herein, we report the use of bipolar electrochemistry to generate ZnO nanoparticles using deionized water and a zinc metal to conform to green chemistry practices. TEM imaging demonstrated that the sizes of the bipolar-made ZnO particles were smaller than the commercial sample. The presence of structural defects in ZnO was correlated with the chemical shifts analyzed by X-ray photoelectron spectroscopy (XPS) and by different concentrations of O2- ions in stoichiometric and defected lattice. Further, the diffuse

SUBMITTER: Hakimian A 

PROVIDER: S-EPMC6384836 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature