Diamondoid Supramolecular Coordination Frameworks from Discrete Adamantanoid Platinum(II) Cages.

ABSTRACT: Recently, porous framework materials with various network-type structures have been constructed via several different approaches, such as coordination interactions, reversible covalent bonds, and non-covalent interactions. Here, we have combined the concepts of supramolecular coordination complex (SCC) and metal-organic framework to offer a new strategy to construct a diamondoid supramolecular coordination framework (SCF) from an adamantanoid supramolecular coordination cage as the tetrahedral node and a difunctional Pt(II) ligand as the linear linker via stepwise orientation-induced supramolecular coordination. The adamantanoid supramolecular coordination cage has four uncoordinated pyridyl groups, which serve as the four vertexes of the tetrahedral geometry in the diamondoid framework. A

SUBMITTER: Cao L 

PROVIDER: S-EPMC6385592 | biostudies-literature | 2018 Jun

REPOSITORIES: biostudies-literature