Self-Healable Supramolecular Vanadium Pentoxide Reinforced Polydimethylsiloxane-Graft-Polyurethane Composites.

ABSTRACT: The self-healing ability can be imparted to the polymers by different mechanisms. In this study, self-healing polydimethylsiloxane-graft-polyurethane (PDMS-g-PUR)/Vanadium pentoxide (V₂O₅) nanofiber supramolecular polymer composites based on a reversible hydrogen bonding mechanism are prepared. V₂O₅ nanofibers are synthesized via colloidal route and characterized by XRD, SEM, EDX, and TEM techniques. In order to prepare PDMS-g-PUR, linear aliphatic PUR having one ⁻COOH functional group (PUR-COOH) is synthesized and grafted onto aminopropyl functionalized PDMS by EDC/HCl coupling reaction. PUR-COOH and PDMS-g-PUR are characterized by ¹H NMR, FTIR. PDMS-g-PUR/V₂O₅ nanofiber composites are prepared and characterized by DSC/TGA, FTIR, and tensile tests. The self-healing ability of PDMS-graft-P

SUBMITTER: Berkem AS 

PROVIDER: S-EPMC6401741 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature