Fabrication of Reactive Poly(Phenyl-Substituted Siloxanes/Silsesquioxanes) with Si‒H and Alkoxy Functional Groups via the Piers⁻Rubinsztajn Reaction.

ABSTRACT: Poly(phenyl-substituted siloxanes/silsesquioxanes) are obtained by the Piers⁻Rubinsztajn (PR) reaction of hydrogen-containing siloxanes (HCS) with diphenyldialkoxysilanes such as diphenyldimethoxysilane and diphenyldiethoxysilane catalyzed by tris(pentafluorophenyl)borane. 29Si nuclear magnetic resonance (NMR) spectroscopy, gel permeation chromatography, and refractive index analysis revealed that apart from phenyl substituents and complex structures such as molecular bridges composed of D₂Ph2[(C₆H₅)₂Si(OSi)₂], structures also existed in these polymers, having high refractive indexes (above 1.50) and high molecular weights (75.60 KDa·mol-1). As revealed by thermogravimetric analysis, these polymers have high thermal stability as well, with temperature at 5% mass loss (T5%) increasing by 18

SUBMITTER: Yi M 

PROVIDER: S-EPMC6403990 | biostudies-literature | 2018 Sep

REPOSITORIES: biostudies-literature