Femtosecond Spectroscopy of Au Hot-Electron Injection into TiO₂: Evidence for Au/TiO₂ Plasmon Photocatalysis by Bactericidal Au Ions and Related Phenomena.

ABSTRACT: In the present work, we provide evidence for visible light irradiation of the Au/TiO₂ nanoparticles' surface plasmon resonance band (SPR) leading to electron injection from the Au nanoparticles to the conduction band of TiO₂. The Au/TiO₂ SPR band is shown to greatly enhance the light absorption of TiO₂ in the visible region. Evidence is presented for the light absorption by the Au/TiO₂ plasmon bands leading to the dissolution of Au nanoparticles. This dissolution occurs concomitantly with the injection of the hot electrons generated by the Au plasmon into the conduction band of TiO₂. The electron injection from the Au nanoparticles into TiO₂ was followed by femtosecond spectroscopy. The formation of Au ions was further confirmed by the spectral shift of the transient absorption spectra of

SUBMITTER: Radzig M 

PROVIDER: S-EPMC6410102 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature