Constructing a Z-scheme Heterojunction of Egg-Like Core@shell CdS@TiO₂ Photocatalyst via a Facile Reflux Method for Enhanced Photocatalytic Performance.

ABSTRACT: A well designed and accurate method of control of different shell thickness and electronic transmission in a Z-scheme core@shell system is conducive to obtaining an optimum photocatalytic performance. Herein, the Z-scheme heterojunction of egg-like core@shell CdS@TiO₂photocatalysts with controlled shell thickness (13 nm, 15 nm, 17 nm, 22 nm) were synthesized by a facile reflux method, and the CdS@TiO₂ structure was proved by a series of characterizations. The photodegradation ratio on methylene blue and tetracycline hydrochloride over the 0.10CdS@TiO₂ composites with TiO₂ shell thickness of 17 nm reached 90% in 250 min and 91% in 5 min, respectively, which was almost 9.8 times and 2.6 times than that of TiO₂ and CdS on rhodamine B respectively under visible light. Besides, the higher total

SUBMITTER: Xue Y 

PROVIDER: S-EPMC6410287 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature