Effects of Fluoro Substitution on the Electrochromic Performance of Alternating Benzotriazole and Benzothiadiazole-Based Donor⁻Acceptor Type Copolymers.

ABSTRACT: Two new donor⁻acceptor type electrochromic copolymers containing non-fluorinated and di-fluorinated benzothiadiazole analogues, namely P(TBT-TBTh) and P(TBT-F-TBTh), were synthesized successfully through chemical polymerization. Both polymers were measured by cyclic voltammetry, UV-vis spectroscopy, colorimetry and thermogravimetric analysis to study the influence of fluoro substitution on the electrochromic performance. The results demonstrated that the two polymer films displayed well-defined redox peaks in pairs during the p-type doping, and showed distinct color change from dark gray blue to light green for P(TBT-TBTh) with the band gap of 1.51 eV, and from gray blue to celandine green for P(TBT-F-TBTh) with the band gap of 1.58 eV. P(TBT-F-TBTh) presented lower highest occupied molecu

SUBMITTER: Zhang Y 

PROVIDER: S-EPMC6414881 | biostudies-literature | 2017 Dec

REPOSITORIES: biostudies-literature