The Coordination and Luminescence of the Eu(III) Complexes with the Polymers (PMMA, PVP).

ABSTRACT: The rare earth complexes and the polymers can be made into composite nanofibers through electrospinning. The fluorescence intensity of these fiber composites is much higher than that of the rare earth complexes. By changing the mixed proportion of polymethyl methacrylate (PMMA) and complexes, nanofiber materials were prepared. Then, by measuring their fluorescence intensity, it is found that the carbonyl bond of PMMA may have coordinated with the rare earth ions and enhanced the luminescence intensity of them. Then, a series of experiments were designed to study their coordination and luminescence mechanism. The coordination mechanism of the polymers with carbonyl groups and the rare earth complexes was explained by Eu(TFT)₃(TPPO), Eu(TFT)₃(TPPO)₂, Eu(PFP)₃(TPPO), Eu(PFP)₃(TPPO)₂, and poly

SUBMITTER: Zhao W 

PROVIDER: S-EPMC6415368 | biostudies-literature | 2018 May

REPOSITORIES: biostudies-literature