The Availability of Neutral Cyan, Green, Blue and Purple Colors from Simple D⁻A Type Polymers with Commercially Available Thiophene Derivatives as the Donor Units.

ABSTRACT: In this paper, the Stille coupling reaction was used to prepare four donor⁻acceptor⁻donor (D⁻A⁻D) type monomers. For this purpose, 2,3-bis(4-methoxyphenyl) quinoxaline was used as the acceptor unit, and thiophene derivatives (3,4-ethylenedioxythiophene, or EDOT; 3-methoxythiophene, or MOTh; 3-methylthiophene, or MTh; and thiophene, or Th) were used as the donor units. The monomers were polymerized to the corresponding polymers by the cyclic voltammetry (CV) or potentiostatic method. The band gaps and the adsorption profiles of the polymers were finely tuned with the incorporation of the different thiophene units. All four polymers have low band gaps, and switched between the colored neutral states and the highly transmissive oxidized state. We were successfully able to obtain the valuable

SUBMITTER: Kong L 

PROVIDER: S-EPMC6418635 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature