Allylthioketone Mediated Free Radical Polymerization of Methacrylates.

ABSTRACT: By combination of high trapping free radical efficiency of the thioketone and resonance of the allylic radical, a new type of mediating agent, 1,3,3-triphenylprop-2-ene-1-thione (TPPT) has been successfully synthesized, and then is used to study controlled free radical polymerization of methacrylates. Very stable TPPT radicals at the end of poly(methyl methacrylate) (PMMA) are detected in the polymerization of MMA using TPPT and AIBN as the control agent and initiator. The MALDI-TOF MS spectra are used to identify terminal groups of the resultant poly(glycidyl methacrylate) (PGMA), and major component of the obtained polymer has the structure, (CH₃)₂(CN)C-PGMA-C₇H₉O₃. Chain extension reaction tests ascertain formation of the dead polymers during the polymer storage and purification process

SUBMITTER: Zhong F 

PROVIDER: S-EPMC6418703 | biostudies-literature | 2017 Nov

REPOSITORIES: biostudies-literature