Synthesis of Novel Hyperbranched Polybenzo-Bisthiazole Amide with Donor⁻Acceptor (D-A) Architecture, High Fluorescent Quantum Yield and Large Stokes Shift.

ABSTRACT: Two novel highly fluorescent hyperbranched polybenzobisthiazole amides with a donor⁻acceptor architecture and large Stokes shift were rationally designed and synthesized. The chemical structures of the prepared hyperbranched polymers were characterized using Fourier Transform Infrared Spectroscopy (FTIR) analysis, Hydrogen Nuclear Magnetic Resonance (¹H-NMR) analysis, and Gel Permeation Chromatography (GPC) analysis. These two polymers were soluble in dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF), and their DMSO and DMF solutions emitted strong green light (517⁻537 nm) with high quantum yields (QYs) and large Stokes shifts. Their relative fluorescence QYs in the DMSO solution were calculated as 77.75% and 81.14% with the Stokes shifts of 137 nm (0.86 eV) and 149 nm (0.92 eV) fo

SUBMITTER: Hu X 

PROVIDER: S-EPMC6418910 | biostudies-literature | 2017 Jul

REPOSITORIES: biostudies-literature