Fabrication of Phosphate-Imprinted PNIPAM/SiO₂ Hybrid Particles and Their Phosphate Binding Property.

ABSTRACT: A SiO₂ microsphere imprinted by phosphate ions was prepared with the use of phosphate ion as the template molecule and tetraethoxysilane as the precursor. Thereafter, the imprinted SiO₂ microspheres were modified with 3-(trimethoxysilyl)propyl methacrylate (TMSPMA@SiO₂), followed by introducing the double bond. In the presence of TMSPMA@SiO₂, using N-isopropylacrylamide as monomer, and potassium persulfate as initiator, polymer/inorganic hybrid particles (PNIPAM/SiO₂) were prepared. Fourier transform infrared spectroscopy, thermogravimetric analysis, nitrogen adsorption-desorption test, and transmission electron microscope were employed for the characterization of molecular imprinted SiO₂ microspheres and PNIPAM/SiO₂ hybrid particles. The effects of phosphate concentration, pH value

SUBMITTER: Cao Z 

PROVIDER: S-EPMC6419039 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature