Synthesis of PNVP-Based Copolymers with Tunable Thermosensitivity by Sequential Reversible Addition⁻Fragmentation Chain Transfer Copolymerization and Ring-Opening Polymerization.

ABSTRACT: Through the reversible addition⁻fragmentation chain transfer (RAFT) copolymerization of 3-ethyl-1-vinyl-2-pyrrolidone (C₂NVP) and N-vinylpyrrolidone (NVP), a series of well-defined P(C₂NVP-co-NVP) copolymers were synthesized (M_n = ca. 8000 to 16,000 and M_w/M_n <1.5) by using a difunctional chain transfer agent, S-(1-methyl-4-hydroxyethyl acetate) O-ethyl xanthate (MHEX). Copolymerizing kinetics and different monomer ratio in feeds were conducted to study the apparent monomer reaction rate and reactivity ratios of NVP and C₂NVP, which indicated similar reaction rates and predominantly ideal random copolymers for the two monomers. The T_gs of the obtaining P(C₂NVP-co-NVP) copolymers signi

SUBMITTER: Huang YS 

PROVIDER: S-EPMC6431924 | biostudies-literature | 2017 Jun

REPOSITORIES: biostudies-literature