Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides.

ABSTRACT: Molecular uranium-nitrides are now well known, but there are no isolable molecular thorium-nitrides outside of cryogenic matrix isolation experiments. We report that treatment of [M(Tren^DMBS)(I)] (M = U, 1; Th, 2; Tren^DMBS = {N(CH₂CH₂NSiMe₂Bu ^t )₃}^3-) with NaN₃ or KN₃, respectively, affords very rare examples of actinide molecular square and triangle complexes [{M(Tren^DMBS)(μ-N₃)} _n ] (M = U, n = 4, 3; Th, n = 3, 4). Chemical reduction of 3 produces [{U(Tren^DMBS)}₂(μ-N)][K(THF)₆] (5) and [{U(Tren^DMBS)}₂(μ-N)] (6), where

SUBMITTER: Du J 

PROVIDER: S-EPMC6446963 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature