Thermoinduced structural-transformation and thermochromic luminescence in organic manganese chloride crystals.

ABSTRACT: The [Mn₂Cl₉]^5- mode of red emissive (C₄NOH₁₀)₅Mn₂Cl₉·C₂H₅OH under thermal treatment will be cleaved into [MnCl₄]^2- in the green emissive (C₄NOH₁₀)₂MnCl₄ with the departure of ethanol. The rapid conversion of luminescence from red to green provides new insight into the luminescence origin and thermal stability of organic-inorganic metal halide hybrids.

SUBMITTER: Sun ME 

PROVIDER: S-EPMC6457203 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature