Topologically immobilized catalysis centre for long-term stable carbon dioxide reforming of methane.

ABSTRACT: Methane reforming at low temperatures is of growing importance to mitigate the environmental impact of the production of synthesis gas, but it suffers from short catalyst lifetimes due to the severe deposition of carbon byproducts. Herein, we introduce a new class of topology-tailored catalyst in which tens-of-nanometer-thick fibrous networks of Ni metal and oxygen-deficient Y₂O₃ are entangled with each other to form a rooted structure, i.e., Ni#Y₂O₃. We demonstrate that the rooted Ni#Y₂O₃ catalyst stably promotes the carbon-dioxide reforming of methane at 723 K for over 1000 h, where the performance of traditional supported catalysts such as Ni/Y₂O₃ diminishes within 100 h due to the precluded m

SUBMITTER: Shoji S 

PROVIDER: S-EPMC6461125 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature