Effect of molecular architecture on ring polymer dynamics in semidilute linear polymer solutions.

ABSTRACT: Understanding the dynamics of ring polymers is a particularly challenging yet interesting problem in soft materials. Despite recent progress, a complete understanding of the nonequilibrium behavior of ring polymers has not yet been achieved. In this work, we directly observe the flow dynamics of DNA-based rings in semidilute linear polymer solutions using single molecule techniques. Our results reveal strikingly large conformational fluctuations of rings in extensional flow long after the initial transient stretching process has terminated, which is observed even at extremely low concentrations (0.025 c^*) of linear polymers in the background solution. The magnitudes and characteristic timescales of ring conformational fluctuations are determined as functions of flow strength and

SUBMITTER: Zhou Y 

PROVIDER: S-EPMC6465312 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature