Hot electron-driven electrocatalytic hydrogen evolution reaction on metal-semiconductor nanodiode electrodes.

ABSTRACT: Hot electrons generated on metal catalysts influence atomic and molecular processes, leading to hot electron-driven catalytic reactions. Here, we show the acceleration of electrocatalytic hydrogen evolution caused by internal injection of hot electrons on Pt/Si metal-semiconductor electrodes. When a forward bias voltage is applied to the Pt/Si contact, hot electrons are injected. The excess energy of these electrons allows them to reach the Pt/electrolyte interface and reduce the adsorbed hydrogen ions to form H₂ (2H⁺ + 2e^-→H₂). We show that the onset potential of the hydrogen evolution reaction shifts positively by 160 mV while the cathodic current exhibits an 8-fold increase in the presence of hot electrons. The effect disappears when the thick

SUBMITTER: Nedrygailov II 

PROVIDER: S-EPMC6470139 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature