Photochemical Synthesis of cis,trans,cis-1,2,3,4-Tetrakis(diphenylphosphanyl)buta-1,3-diene and Its Metal Coordination.

ABSTRACT: The new bis(bidentate) tetraphosphane cis,trans,cis-1,2,3,4-tetrakis(diphenylphosphanyl)buta-1,3-diene (dppbd) (7) was obtained by applying a photochemical synthetic protocol. The key step of the photochemical reaction consisted of an intramolecular [2+2] cycloaddition involving a C-C double and triple bond of the Pt-dimer species of the formula [Pt₂Cl₄(dppa)(trans-dppen)] (2) {dppa = 1,2-bis(diphenylphosphanyl)acetylene and dppen = 1,2-bis(diphenylphosphanyl)ethene} leading to [Pt₂Cl₄(dppbd)] (5). The asymmetrically bridged precursor complex 2 was obtained by combinatorial chemistry. Single crystal X-ray structure analyses of 2 and 5 proved that the intramolecular photochemica

SUBMITTER: Prock J 

PROVIDER: S-EPMC6471117 | biostudies-literature | 2018 Dec

REPOSITORIES: biostudies-literature