Structured Monolithic Catalysts vs. Fixed Bed for the Oxidative Dehydrogenation of Propane.

ABSTRACT: The deposition of V-based catalysts for the oxidative dehydrogenation of propane to propene on cordierite honeycomb monoliths was optimised as a strategy to decrease the contact time in a structured reactor with respect to a conventional fixed bed one. 10 wt% VOx supported over SiO₂ or Al₂O₃ were used as catalysts, deposed over the monolith using silica or alumina as primer, respectively. Both the alumina supported catalyst and the bohemite primer precursor were effectively deposed by dip-coating from stable powder suspensions, whereas insufficient adhesion was obtained when loading pre-synthesised SiO₂ over the cordierite. A new method based on sol-gel production of SiO₂ from tetraethylortosilicate (TEOS) over the monolith surface was set up. A correlation was derived for the prevision of

SUBMITTER: Rossetti I 

PROVIDER: S-EPMC6471166 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature