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Supramolecular chirality transformation driven by monodentate ligand binding to a coordinatively unsaturated self-assembly based on C ₃-symmetric ligands.

ABSTRACT: Monodentate ligand binding is facilitated by supramolecular chirality transformations from propeller-shaped chirality into single-twist chirality by altering the self-assembly of C ₃-symmetric chiral ligands. The C ₃-symmetric chiral ligands (Im ^R ₃Bz and Im ^S ₃Bz) contain three chiral imidazole side arms (Im ^R and Im ^S ) at the 1,3,5-positions of a central benzene ring. Upon coordination to zinc ions (Zn²⁺), which have a tetrahedral coordination preference, the C ₃-symmetric chiral ligands assemble, in a stepwise manner, into a propeller-shaped assembly with a general formula (Im⁽ ^R

SUBMITTER: Imai Y

PROVIDER: S-EPMC6471804 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

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Supramolecular chirality transformation driven by monodentate ligand binding to a coordinatively unsaturated self-assembly based on C ₃-symmetric ligands.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Supramolecular chirality transformation driven by monodentate ligand binding to a coordinatively unsaturated self-assembly based on C 3-symmetric ligands.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Supramolecular chirality transformation driven by monodentate ligand binding to a coordinatively unsaturated self-assembly based on C ₃-symmetric ligands.