Donor-acceptor-stabilised germanium analogues of acid chloride, ester, and acyl pyrrole compounds: synthesis and reactivity.

ABSTRACT: Germaacid chloride, germaester, and N-germaacyl pyrrole compounds were not known previously. Therefore, donor-acceptor-stabilised germaacid chloride (i-Bu)₂ATIGe(O)(Cl) → B(C₆F₅)₃ (1), germaester (i-Bu)₂ATIGe(O)(OSiPh₃) → B(C₆F₅)₃ (2), and N-germaacyl pyrrole (i-Bu)₂ATIGe(O)(NC₄H₄) → B(C₆F₅)₃ (3) compounds, with Cl-Ge[double bond, length as m-dash]O, Ph₃SiO-Ge[double bond, length as m-dash]O, and C₄H₄N-Ge[double bond, length as m-dash]O moieties, respectively, are reported here. Germaacid chloride 1 reacts with PhCCLi, KOt-Bu, and RLi (R = Ph, Me)

SUBMITTER: Sharma MK 

PROVIDER: S-EPMC6472437 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature