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Spiderweb-Like Fe-Co Prussian Blue Analogue Nanofibers as Efficient Catalyst for Bisphenol-A Degradation by Activating Peroxymonosulfate.


ABSTRACT: Prussian blue and its analogues (PBA) based nanomaterials have been widely applied to removing pollutants in the recent years. However, easy aggregation and poor recycling largely limit their practical applications. In this work, spiderweb-like Fe-Co Prussian blue analogue/polyacrylonitrile (FCPBA/PAN) nanofibers were prepared by electrospinning and applied to degrading bisphenol-A (BPA) by activating peroxymonosulfate (PMS). Detailed characterization demonstrated that a high loading of FCPBA (86% of FCPBA in FCPBA/PAN) was successfully fixed on the PAN nanofibers. 67% of BPA was removed within 240 min when 500 mg·L-1 PMS and 233 mg·L-1 FCPBA/PAN were introduced in 20 mg·L-1 BPA solution at initial pH of 2.8. Electron paramagnetic resonance (EPR) and radical inhibition experiments were per

SUBMITTER: Wang H 

PROVIDER: S-EPMC6473942 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature