Utilizing Infrared Spectroscopy to Analyze the Interfacial Structures of Ionic Liquids/Al₂O₃ and Ionic Liquids/Mica Mixtures under High Pressures.

ABSTRACT: The interfacial interactions between ionic liquids (1,3-dimethylimidazolium methyl sulfate and 1-ethyl-3-methylimidazolium trifluoromethanesulfonate) and solid surfaces (mesoporous aluminum oxide and mica) have been studied by infrared spectroscopy at high pressures (up to 2.5 GPa). Under ambient pressure, the spectroscopic features of pure ionic liquids and mixtures of ionic liquids/solid particles (Al₂O₃ and mica) are similar. As the pressure is increased, the cooperative effect in the local structure of pure 1,3-dimethylimidazolium methyl sulfate becomes significantly enhanced as the imidazolium C⁻H absorptions of the ionic liquid are red-shifted. However, this pressure-enhanced effect is reduced by adding the solid particles (Al₂O₃ and mica) to 1,3-dimethylimidazolium methyl sulfate. A

SUBMITTER: Chang YH 

PROVIDER: S-EPMC6473959 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature