The Effect of Chloride Anions on Charge Transfer in Dye-Sensitized Photoanodes for Water Splitting.

ABSTRACT: The photoelectrochemical behavior of dye-sensitized photoelectrochemical cells based on a TiO₂ layer sensitized with ruthenium components, including an absorber, ruthenium(II)bis(2,2'-bipyridine)([2,2'-bipyridine]-4,4'-diylbis(phosphonic acid)) dibromide (RuP), and a catalyst, ruthenium(II) tris(4-methylpyridine)(4-(4-(2,6-bis((l1-oxidanyl)carbonyl)pyridin-4-yl)phenyl) pyridine-2,6-dicarboxylic acid) (RuOEC), was investigated in the following water-based electrolyte configurations: KCl (pH ≈ 5), HCl (pH ≈ 3), ethylphoshonic acid (pH ≈ 3) with a different KCl concentration, and a standard phosphate buffer (pH ≈ 7). The rate of charge transfer on the photoanode's surface was found to increase in line with the increase in the concentration of chloride anions (Cl^-) in the

SUBMITTER: Gradzka I 

PROVIDER: S-EPMC6477621 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature