Path-Dependent Preparation of Complex Micelle Packings of a Hydrated Diblock Oligomer.

ABSTRACT: Small-angle X-ray scattering analyses reveal that the hydrated diblock oligomer n-C₁₆H₂₃(OCH₂CH₂)₂₀-OH (C₁₆E₂₀ or Brij 58) forms lyotropic liquid crystals (LLCs) exhibiting face-centered cubic (FCC), body-centered cubic (BCC), Frank-Kasper (FK) A15, and cylindrical (H_I) morphologies over the concentration range 30-65 wt % amphiphile. Heating LLCs comprising 54-59 wt % C₁₆E₂₀ drives the temperature-dependent phase transition sequence: A15 → BCC → H_I. However, rapidly quenching the resulting H_I phase from 70 to 25 °C initially forms a BCC phase that isothermally transforms into a complex, tetragonal FK σ phase comprising 30 quasispherical micelles. The me

SUBMITTER: Jayaraman A 

PROVIDER: S-EPMC6487539 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature