Aqueous acid-based synthesis of lead-free tin halide perovskites with near-unity photoluminescence quantum efficiency.

ABSTRACT: Recently, lead halide perovskites with outstanding emission performance have become new candidate materials for light-emitting devices and displays; however, the toxicity of lead and instability of halide perovskites remain significant challenges. Herein, we report the aqueous acid-based synthesis of highly emissive two-dimensional (2D) tin halide perovskites, (octylammonium)₂SnX₄ (X = Br, I, or mixtures thereof), which displayed a high absolute photoluminescence (PL) quantum yield of near-unity in the solid-state, PL emission centered at 600 nm with a broad bandwidth (136 nm), a large Stokes shift (250 nm), long-lived luminescence (τ = 3.3 μs), and zero overlap between their absorption and emission spectra. Significantly, the stability study of 2D tin halide p

SUBMITTER: Wang A 

PROVIDER: S-EPMC6492635 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature