A light-driven burst of hydroxyl radicals dominates oxidation chemistry in newly activated cloud droplets.

ABSTRACT: Aerosol particles and their interactions with clouds are one of the most uncertain aspects of the climate system. Aerosol processing by clouds contributes to this uncertainty, altering size distributions, chemical composition, and radiative properties. Many changes are limited by the availability of hydroxyl radicals in the droplets. We suggest an unrecognized potentially substantial source of OH formation in cloud droplets. During the first few minutes following cloud droplet formation, the material in aerosols produces a near-UV light-dependent burst of hydroxyl radicals, resulting in concentrations of 0.1 to 3.5 micromolar aqueous OH ([OH]_aq). The source of this burst is previously unrecognized chemistry between iron(II) and peracids. The contribution of the "OH burst" to tot

SUBMITTER: Paulson SE 

PROVIDER: S-EPMC6494489 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature