Decarboxylative hydrazination of unactivated carboxylic acids by cerium photocatalysis.

ABSTRACT: We report the cerium photocatalyzed radical decarboxylative hydrazination of carboxylic acids with di-tert-butylazodicarboxylate (DBAD). The operationally simple protocol provides rapid access to synthetically useful hydrazine derivatives and overcomes current scope limitations in the photoredox-catalyzed decarboxylation of carboxylic acids.

SUBMITTER: Yatham VR 

PROVIDER: S-EPMC6498423 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature