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Crystal structures of binuclear complexes of gadolinium(III) and dysprosium(III) with oxalate bridges and chelating N,N'-bis-(2-oxido-benz-yl)-N,N'-bis-(pyridin-2-ylmeth-yl)ethyl-enedi-amine (bbpen^2-).

ABSTRACT: The reaction between mononuclear [Ln(bbpen)Cl] [Ln = Gd or Dy; H₂bbpen = N,N'-bis-(2-hy-droxy-benz-yl)-N,N'-bis-(pyridin-2-ylmeth-yl)ethyl-enedi-amine, C₂₈H₃₀N₄O₂] and potassium oxalate monohydrate in water/methanol produced the solvated centrosymmetric isostructural binuclear (μ-oxalato)bis-{[N,N'-bis-(2-oxidobenzyl-κO)-N,N'-bis-(pyridin-2-ylmethyl-κN)ethyl-enedi-amine-κ² N,N']dilanthanide(III)}-methanol-water (1/4/4) complexes, [Ln ₂(C₂₈H₂₈N₄O₂)₂(C₂O₄)]·4CH₃OH·4H₂O, with lanthanide(III) = gadolinium(III) (Ln<

SUBMITTER: Barbosa GA

PROVIDER: S-EPMC6509678 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

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Crystal structures of binuclear complexes of gadolinium(III) and dysprosium(III) with oxalate bridges and chelating N,N'-bis-(2-oxido-benz-yl)-N,N'-bis-(pyridin-2-ylmeth-yl)ethyl-enedi-amine (bbpen^2-).

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Dataset Information

Crystal structures of binuclear complexes of gadolinium(III) and dysprosium(III) with oxalate bridges and chelating N,N'-bis-(2-oxido-benz-yl)-N,N'-bis-(pyridin-2-ylmeth-yl)ethyl-enedi-amine (bbpen2-).

OmicsDI is part of the ELIXIR infrastructure

Tweets

Crystal structures of binuclear complexes of gadolinium(III) and dysprosium(III) with oxalate bridges and chelating N,N'-bis-(2-oxido-benz-yl)-N,N'-bis-(pyridin-2-ylmeth-yl)ethyl-enedi-amine (bbpen^2-).