Redetermination of the crystal structure of 2-oxo-1,3-thia-zolidin-4-iminium chloride.

ABSTRACT: In the redetermination of the title compound, C₃H₅N₂OS⁺·CI^-, the asymmetric unit consists of one independent 2-oxo-1,3-thia-zolidin-4-iminium cation and one independent chloride anion. The cation inter-acts with a chloride anion via N-H⋯Cl hydrogen bonds forming a supra-molecular chain along [010]. These supra-molecular chains are further extended by weak C-H⋯Cl and C-H⋯O inter-actions, forming a two-dimensional network parallel to (001). The crystal structure is further stabilized by weak C-O⋯π inter-actions, supporting a three-dimensional architecture. The structure was previously determined by Ananthamurthy & Murthy [Z. Kristallogr. (1975). 8, 356-367] but has been redetermined with higher precision to allow the

SUBMITTER: Muthukkumar M 

PROVIDER: S-EPMC6509681 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature