Conformer-dependent self-assembled metallacycles with photo-reversible response.

ABSTRACT: Discrete, well-defined metallacycles and metallacages with stimuli-responsive behaviors have been largely predominated by the organic donor/metal acceptor paradigm with spontaneous formation of coordination bonds. However, light-driven self-assembly systems usually show relatively low utilization yield of photons and low fatigue resistance. Given that almost no example illustrates the different self-assembly behaviors of antiparallel and parallel conformers in the traditional photochromic diarylethene (DAE) system, here we have for the first time constructed a unique series of photoactive conformer-dependent metallacycles, focusing on the characterization and comparison of self-assembly behavior in different ligand conformers with different di-platinum(ii) acceptors. Their photoswitchable

SUBMITTER: Li M 

PROVIDER: S-EPMC6510319 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature