Copper Complexes of Multidentate Carboxamide Ligands.

ABSTRACT: The copper coordination chemistry of two multidentate carboxamido ligands derived from HL¹ (offering two quinolyl and one carboxamide donor) and H₄L² (with two pyridine(dicarboxamido) units linked by naphthalene spacers) was explored. The former was chosen because upon deprotonation it would provide a monoanionic mer-coordinating N-donor set that would model the putative deprotonated form of the His-brace in copper monooxygenases, while the latter was designed to bind two copper ions and enable comparisons to other systems with different ligand spacers. Upon reaction with Cu(I)-mesityl, HL¹ yielded a symmetric dimer (L¹Cu)₂ in which each bis(quinolyl)amide ligand binds via two N-donors to one Cu(I) ion and via

SUBMITTER: Elwell CE 

PROVIDER: S-EPMC6519725 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature